93033790.259
���f���P�C�f�N���X�^�[�̐����@�\
����@�H
���˖�q����C����N��C�z���j
Abstract
Si2H6�̔M�����ɂ�萅�f���P�C�f�N���X�^�[�̐����@�\�ɂ��āA�^�O���[�U�[���C�I������s���Ԏ��ʕ��͖@�y�є����V�~�����[�V�����ɂ�茟�������B�������x�̏㏸�ƂƂ��ɁAH2�̒E���ߒ����Ƃ��Ȃ�SinH2n�ASinH2n-2�̐����̑������m�F���ꂽ�B
Detectionofhydrogenatedsiliconclustersduringthermaldecompositionofdisilaneinaflowreactorwasperformedusingtime-of-flightmassspectrometrycoupledwithvacuumultravioletphotoionizationinatemperaturerangeof298-860K TheSinH2n+2,SinH2n,SinH2n-2,andSinH2n-4containinguptotensiliconatomswereobservedasgas-phaseproductsduringthedisilanepyrolysis