| 有機-無機複合電子系の構築を目的に，遷移金属イオンを対カチオンとしてもつNi(dmit)2塩の合成を行った．遷移金属イオンのd電子とNi(dmit)2のπ電子が直接相互作用するM-[Ni(dmit)2]系と，配位子π系を介して間接的に相互作用するM-L(π)-[Ni(dmit)2]系の構造と物性について報告する． |
| The Ni(dmit)2-based salts with transition metal ions incorporated as counter cations have been prepared. The physical properties of two kinds of salts will be discussed; one is the M-Ni(dmit)2 salt in which d electrons of metal ions directly interact with p electrons of Ni(dmit)2. The other is the M-L(p)-Ni(dmit)2 salt where d and p electrons indirectly interact via ligand p conjugated systems. |